\begin{document}
\begin{tikzpicture}[scale=2, ultra thick,
every node/.style={draw=black, circle, very thick, font =\huge, minimum size=3em},
level 1/.style={sibling distance=4em/1, level distance=4em},%横向距离与纵向距离
level 2/.style={sibling distance=4em/2, level distance=4em},
level 3/.style={sibling distance=4em/1, level distance=4em},
]
\node(1) {S1}
child {node (2) {S2}
child {node (4) {S4}}
child {node (5) {S5}}
}
child {node[draw=red, fill=red!50] (3) {S3}
child {node[rectangle, xshift=2.5cm] (6) {S6}}
};
\end{tikzpicture}
\end{document}